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Exploring the coupling relationship of industrial agglomeration and low-carbon economy considering spatiotemporal

《工程管理前沿（英文）》 2023年 第10卷 第2期   页码 285-299 doi: 10.1007/s42524-022-0197-1

摘要： Although China’s construction machinery thrives to meet the needs of construction, a number of challenges still remain to be overcome, such as lack of thorough knowledge of regional disparities and several limitations in terms of carbon emissions and economic development. Meanwhile, a low-carbon economy was proposed and implemented in China. This research aims to investigate the differences in industrial agglomeration of construction machineries and further explore the relationship between industrial agglomeration and low-carbon economy. On this basis, spatiotemporal analysis was performed to evaluate the levels of industrial agglomeration in different regions based on the situations of China’s construction machinery industry. Furthermore, this study explored the interaction between industrial agglomeration and low-carbon economy utilizing the coupling coordination analysis method. Results showed that the coupling coordination of the two subsystems was extremely unbalanced in 2006, and it maintained an increasing trend, reaching a relatively high level in 2018. Finally, suggestions, such as establishing a policy guarantee system and implementing variable policies in different regions, were proposed to provide guidelines for the government decision-making and promote the sustainable development of China’s construction machinery industry.

关键词： spatiotemporal differentiation     industrial agglomeration     low-carbon economy     construction machinery industry     empirical study    

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Coupling and evolution mechanism of infrastructure mega-projects complex ecosystem: Case study on Hong

Zebin ZHAO, Xiaolong XUE, Xinglin GAO, Gang LIU, Hengqin WU

《工程管理前沿（英文）》 2018年 第5卷 第1期   页码 17-29 doi: 10.15302/J-FEM-2018080

摘要： Infrastructure mega-projects (IMP), which involve complex interactions and feedback, have more significant impact on economic, social, and other systems. This paper proposes a concept—the IMP complex ecosystem—to analyze IMP from a broad perspective of organic links across engineering, social, economic, and resource environments. Moreover, this paper proposes the theoretical concept, framework, and functions for the IMP complex ecosystem based on complex ecosystem theory. First, the coupling process between IMP complex ecosystem subsystems is analyzed through material flows, energy flows, information flows, and value streams. Second, a logistic model of the IMP complex ecosystem is proposed by analyzing the evolution conditions and motivations. Third, the evolution pattern of the IMP complex ecosystem is determined. Fourth, the positive evolution strategy of the IMP complex ecosystem based on dissipative structure theory and the influencing factors of the evolutionary process is introduced. Finally, the Hong Kong-Zhuhai-Macao Bridge and are used as the case study. This paper also analyzes the coupling structure on the complex ecosystem of the Hong Kong-Zhuhai-Macao Bridge and investigates the coupling and evolution mechanism application of the IMP complex ecosystem on protection for the Hong Kong-Zhuhai-Macao Bridge project.

关键词： infrastructure mega-projects (IMP)     Hong Kong-Zhuhai-Macao Bridge     complex ecosystem     coupling relationship     evolution mechanism    

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非独立同分布推荐系统：推荐范式转换的综述和框架 Artical

Longbing Cao

《工程（英文）》 2016年 第2卷 第2期   页码 212-224 doi: 10.1016/J.ENG.2016.02.013

摘要：

虽然推荐系统在我们的生活、学习、工作和娱乐中扮演着越来越重要的角色，但是很多时候我们收到的推荐都是不相关的、重复的，或者包含不感兴趣的产品和服务。这些差的推荐系统产生的原因来源于一个本征假设：传统的理论和推荐系统认为用户和物品是独立同分布的(IID)。另一个明显的现象是，虽然投入了很多的精力模拟用户或者物品的特殊属性，但用户和物品的总体属性及它们之间的非独立同分布性(non-IID) 被忽略了。本文先讨论了推荐系统的非独立同分布性，紧接着介绍了非独立同分布性原理，目的是从耦合和异构性的角度来深入阐述传统的推荐系统的固有本质。这种非独立同分布推荐系统引起了传统推荐系统范式的转化—— 从独立同分布向非独立同分布进行转化，希望能够形成高效的、相关性高的、个人订制和可操作的推荐系统。这种系统创造了令人兴奋的能够解决包含冷启动、以稀疏数据为基础、跨域、基于群组信息和欺诈攻击等各种复杂情况的新的研究方向和解决方案。

关键词： 独立同分布     非独立同分布     异构性     关系耦合     耦合学习     关系学习     独立同分布学习     非独立同分布学习     推荐系统     推荐     非独立同分布推荐    

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Microdamage study of granite under thermomechanical coupling based on the particle flow code

《结构与土木工程前沿（英文）》   页码 1413-1427 doi: 10.1007/s11709-023-0953-2

摘要： The thermomechanical coupling of rocks refers to the interaction between the mechanical and thermodynamic behaviors of rocks induced by temperature changes. The study of this coupling interaction is essential for understanding the mechanical and thermodynamic properties of the surrounding rocks in underground engineering. In this study, an improved temperature-dependent linear parallel bond model is introduced under the framework of a particle flow simulation. A series of numerical thermomechanical coupling tests are then conducted to calibrate the micro-parameters of the proposed model by considering the mechanical behavior of the rock under different thermomechanical loadings. Good agreement between the numerical results and experimental data are obtained, particularly in terms of the compression, tension, and elastic responses of granite. With this improved model, the thermodynamic response and underlying cracking behavior of a deep-buried tunnel under different thermal loading conditions are investigated and discussed in detail.

关键词： thermomechanical coupling effect     granite     improved linear parallel bond model     thermal property     particle flow code    

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Simulation of steel beam under ceiling jet based on a wind–fire–structure coupling model

《结构与土木工程前沿（英文）》 2023年 第17卷 第1期   页码 78-98 doi: 10.1007/s11709-022-0936-8

摘要： For localized fires, it is necessary to consider the thermal and mechanical responses of building elements subject to uneven heating under the influence of wind. In this paper, the thermomechanical phenomena experienced by a ceiling jet and I-beam in a structural fire were simulated. Instead of applying the concept of adiabatic surface temperature (AST) to achieve fluid–structure coupling, this paper proposes a new computational fluid dynamics–finite element method numerical simulation that combines wind, fire, thermal, and structural analyses. First, to analyze the velocity and temperature distributions, the results of the numerical model and experiment were compared in windless conditions, showing good agreement. Vortices were found in the local area formed by the upper and lower flanges of the I-beam and the web, generating a local high-temperature zone and enhancing the heat transfer of convection. In an incoming-flow scenario, the flame was blown askew significantly; the wall temperature was bimodally distributed in the axial direction. The first temperature peak was mainly caused by radiative heat transfer, while the second resulted from convective heat transfer. In terms of mechanical response, the yield strength degradation in the highest-temperature region in windless conditions was found to be significant, thus explaining the stress distribution of steel beams in the fire field. The mechanical response of the overall elements considering the incoming flows was essentially elastic.

关键词： CFD–FEM coupling     steel beam     wind     ceiling jet     numerical heat transfer    

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Influence of freeze–thaw damage gradient on stress–strain relationship of stressed concrete

《结构与土木工程前沿（英文）》   页码 1326-1340 doi: 10.1007/s11709-023-0014-x

摘要： Influence of freeze–thaw damage gradient on stress–strain relationship of stressed concrete

关键词： strain relationship concrete    

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catalysts derived from zeolitic imidazolate framework@MXene composites for efficient oxidative self-coupling

《化学科学与工程前沿（英文）》 2023年 第18卷 第1期 doi: 10.1007/s11705-023-2378-9

摘要： In this study, we synthesize a catalyst comprising cobalt nanoparticles supported on MXene by pyrolyzing a composite in a N2 environment. Specifically, the composite comprises a bimetallic Zn/Co zeolitic imidazole framework grown in situ on the outer surface of MXene. The catalytic efficiency of the catalyst is tested for the self-coupling of 4-methoxybenzylamine to produce value-added imine, where atmospheric oxygen (1 atm) is used as the oxidant. Based on the results, the catalyst displayed impressive catalytic activity, achieving 95.4% yield of the desired imine at 383 K for 8 h. Furthermore, the catalyst showed recyclability and tolerance toward benzylamine substrates with various functional groups. The outstanding performance of the catalyst is primarily attributed to the synergetic catalytic effect between the cobalt nanoparticles and MXene support, while also benefiting from the three-dimensional porous structure. Additionally, a preliminary investigation of potential reaction mechanisms is conducted.

关键词： MXene     sacrificial template     oxidative self-coupling     Co nanoparticles     imine    

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Mesh relationship modeling and dynamic characteristic analysis of external spur gears with gear wear

《机械工程前沿（英文）》 2022年 第17卷 第1期   页码 9-9 doi: 10.1007/s11465-021-0665-z

摘要： Gear wear is one of the most common gear failures, which changes the mesh relationship of normal gear. A new mesh relationship caused by gear wear affects meshing excitations, such as mesh stiffness and transmission error, and further increases vibration and noise level. This paper aims to establish the model of mesh relationship and reveal the vibration characteristics of external spur gears with gear wear. A geometric model for a new mesh relationship with gear wear is proposed, which is utilized to evaluate the influence of gear wear on mesh stiffness and unloaded static transmission error (USTE). Based on the mesh stiffness and USTE considering gear wear, a gear dynamic model is established, and the vibration characteristics of gear wear are numerically studied. Comparison with the experimental results verifies the proposed dynamic model based on the new mesh relationship. The numerical and experimental results indicate that gear wear does not change the structure of the spectrum, but it alters the amplitude of the meshing frequencies and their sidebands. Several condition indicators, such as root-mean-square, kurtosis, and first-order meshing frequency amplitude, can be regarded as important bases for judging gear wear state.

关键词： gear wear     mesh relationship     mesh stiffness     transmission error     vibration characteristics    

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Effect of alkyl nitrite decomposition on catalytic performance of CO coupling reaction over supported

Zhenhua LI, Weihan WANG, Dongxue YIN, Jing LV, Xinbin MA

《化学科学与工程前沿（英文）》 2012年 第6卷 第4期   页码 410-414 doi: 10.1007/s11705-012-1213-5

摘要： The syntheses of dimethyl oxalate (DMO) and diethyl oxalate (DEO) by CO coupling reaction in gaseous phase were investigated in a fixed bed reactor over Pd-Fe/Al O catalyst. The catalytic performance was characterized by CO conversion, space-time yield (STY) and selectivity of DMO (or DEO). The results showed that over Pd-Fe/Al O catalyst, the STY of DMO was higher than that of DEO under the same reaction conditions. The optimum reaction temperatures for synthesizing DMO and DEO were 403 K and 393 K, respectively, at the molar ratio 1 ∶ 1 of alkyl nitrite to CO. The difference in synthesizing DMO and DEO on the same catalyst was attributed to the decomposition performances of methyl nitrite (MN) and ethyl nitrite (EN), as density functional theory (DFT) calculation showed that EN decomposed more easily than MN.

关键词： palladium     CO coupling     dialkyl oxalate     alkyl nitrite     decomposition    

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Thermodynamic and economic analyses of a coal and biomass indirect coupling power generation system

Buqing YE, Rui ZHANG, Jin CAO, Bingquan SHI, Xun ZHOU, Dong LIU

《能源前沿（英文）》 2020年 第14卷 第3期   页码 590-606 doi: 10.1007/s11708-020-0809-6

摘要： The coal and biomass coupling power generation technology is considered as a promising technology for energy conservation and emission reduction. In this paper, a novel coal and biomass indirect coupling system is proposed based on the technology of biomass gasification and co-combustion of coal and gasification gas. For the sake of comparison, a coal and biomass direct coupling system is also introduced based on the technology of co-combustion of coal and biomass. The process of the direct and the indirect coupling system is simulated. The thermodynamic and economic performances of two systems are analyzed and compared. The simulation indicates that the thermodynamic performance of the indirect coupling system is slightly worse, but the economic performance is better than that of the direct coupling system. When the blending ratio of biomass is 20%, the energy and exergy efficiencies of the indirect coupling system are 42.70% and 41.14%, the internal rate of return (IRR) and discounted payback period (DPP) of the system are 25.68% and 8.56 years. The price fluctuation of fuels and products has a great influence on the economic performance of the indirect coupling system. The environmental impact analysis indicates that the indirect coupling system can inhibit the propagation of NO and reduce the environmental cost.

关键词： biomass     indirect coupling system     process simulation     thermodynamic analysis     economic analysis    

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Enhancing the aromatic selectivity of cyclohexane aromatization by CO2 coupling

《化学科学与工程前沿（英文）》 2023年 第17卷 第11期   页码 1801-1808 doi: 10.1007/s11705-023-2325-9

摘要： Improving the aromatic selectivity in the alkane aromatization process is of great importance for its practical utilization but challenge to make because the high H/C ratio of alkanes would lead to a serious hydrogen transfer process and a large amount of light alkanes. Herein, CO2 is introduced into the cyclohexane conversion process on the HZSM-5 zeolite, which can improve the aromatic selectivity. By optimizing the reaction conditions, an improved aromatic (benzene, toluene, xylene, and C9+) selectivity of 48.2% can be obtained at the conditions of 2.7 MPa (CO2), 450 °C, and 1.7 h−1, which is better than that without CO2 (aromatic selectivity = 43.2%). In situ transmission Fourier transform infrared spectroscopy spectra illustrate that many oxygenated chemical intermediates (e.g., carboxylic acid, anhydride, unsaturated aldehydes/ketones or ketene) would be formed during the cyclohexane conversion process in the presence of CO2. 13C isotope labeling experimental results demonstrate that CO2 can enter into the aromatics through the formation of oxygenated chemical intermediates and thereby improve the aromatic selectivity. This study may open a green, economic, and promising way to improve the aromatic selectivity for alkane aromatization process.

关键词： aromatics     carbon dioxide     aromatization     coupling reaction     ZSM-5 zeolite    

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Mild and highly regioselective synthesis of biaryl acids via Rh(I)-catalyzed cross-dehydrogenative coupling

Yun Liu, Youquan Zhu, Chaojun Li

《化学科学与工程前沿（英文）》 2018年 第12卷 第1期   页码 3-8 doi: 10.1007/s11705-017-1693-4

摘要： A mild and efficient synthesis for the biaryl acids via rhodium-catalyzed cross-dehydrogenative coupling reaction has been developed. This novel protocol with sodium chlorite as an oxidant featured many advantages such as mild reaction conditions, high regioselectivity, tolerance of various functional groups, and good to excellent yields.

关键词： biaryl acids     cross-dehydrogenative coupling     rhodium-catalyzed    

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Mapping the structure-activity relationship of

Worawan PANPIPAT, Hasene KESKIN, Zheng GUO

《化学科学与工程前沿（英文）》 2015年 第9卷 第1期   页码 105-113 doi: 10.1007/s11705-015-1502-x

摘要： The phase behavior of twelve synthesized -sitosteryl fatty acid esters with acyl moieties with different chain lengths (C2:0-C18:0) and different degrees of unsaturation (C18:1-C18:3) were investigated in pure and mixed Langmuir monolayers with phospholipids. The surface-pressure isotherms showed that short chain -sitosteryl fatty acid esters gave smaller mean molecular areas and had decreased monolayer stability and the long chain steryl esters did not produce collapsed plateaus. All the steryl esters displayed strong condensing effects, but there was a pronounced structural dependency: medium chain esters (C8 and C10) were less efficient than short and long chain esters. Atomic force microscopy imaging demonstrated that monolayers mixed with dipalmitoyl phosphatidylcholine (DPPC) displayed both DPPC-rich and steryl lipid-rich domains. However, the height and area differences between the two phases and the roughness and morphologic patterns were very dependent on the steryl lipid concentrations as well as the length, the degree of unsaturation and the molecular conformations of the acyl segments. These findings not only provide a better understanding of the interactions between phytosteryl hydrophobic derivatives and biomembranes, but also may be of general use for the design and engineering of phytosterol structural derivations for specific food and pharmaceutical applications.

关键词： β-sitosteryl fatty acid esters     dipalmitoyl phosphatidylcholine     Langmuir monolayer     condensing effect     structure-activity relationship    

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Property-performance relationship of core-shell structured black TiO photocatalyst for environmental

《环境科学与工程前沿（英文）》 2023年 第17卷 第9期 doi: 10.1007/s11783-023-1711-3

摘要：

● Properties and performance relationship of CSBT photocatalyst were investigated.

关键词： Black TiO2     Core-shell structure     Property-performance relationship     Agro-industrial effluent     Environmental remediation    

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Modeling of specific structure crystallization coupling with dissolution

Yuanhui JI, Hongliang QIAN, Chang LIU, Xiaohua LU, Xin FENG, Xiaoyan JI,

《化学科学与工程前沿（英文）》 2010年 第4卷 第1期   页码 52-56 doi: 10.1007/s11705-009-0301-7

摘要： In this paper, the research framework for specific structure crystallization modeling has been proposed in which four steps are required in order to investigate the rigorous crystallization modeling by thermodynamics. The first is the activity coefficient model of the solution, the second is Solid-Liquid equilibrium, the third and fourth are the dissolution and crystallization kinetics modeling, respectively. Our investigations show that the mechanisms of complex structure formation and microphase transition can be analyzed by combining the dissolution and crystallization kinetics modeling. Moreover, the formation mechanism of the porous KCl has been analyzed, which may provide a reference for the porous structure formation in the advanced material synthesis.

关键词： structure crystallization     activity coefficient     reference     KCl     dissolution    

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标题 作者 时间 类型 操作

Exploring the coupling relationship of industrial agglomeration and low-carbon economy considering spatiotemporal

期刊论文

Coupling and evolution mechanism of infrastructure mega-projects complex ecosystem: Case study on Hong

Zebin ZHAO, Xiaolong XUE, Xinglin GAO, Gang LIU, Hengqin WU

期刊论文

非独立同分布推荐系统：推荐范式转换的综述和框架

Longbing Cao

期刊论文

Microdamage study of granite under thermomechanical coupling based on the particle flow code

期刊论文

Simulation of steel beam under ceiling jet based on a wind–fire–structure coupling model

期刊论文

Influence of freeze–thaw damage gradient on stress–strain relationship of stressed concrete

期刊论文

catalysts derived from zeolitic imidazolate framework@MXene composites for efficient oxidative self-coupling

期刊论文

Mesh relationship modeling and dynamic characteristic analysis of external spur gears with gear wear

期刊论文

Effect of alkyl nitrite decomposition on catalytic performance of CO coupling reaction over supported

Zhenhua LI, Weihan WANG, Dongxue YIN, Jing LV, Xinbin MA

期刊论文

Thermodynamic and economic analyses of a coal and biomass indirect coupling power generation system

Buqing YE, Rui ZHANG, Jin CAO, Bingquan SHI, Xun ZHOU, Dong LIU

期刊论文

Enhancing the aromatic selectivity of cyclohexane aromatization by CO2 coupling

期刊论文

Mild and highly regioselective synthesis of biaryl acids via Rh(I)-catalyzed cross-dehydrogenative coupling

Yun Liu, Youquan Zhu, Chaojun Li

期刊论文

Mapping the structure-activity relationship of

Worawan PANPIPAT, Hasene KESKIN, Zheng GUO

期刊论文

Property-performance relationship of core-shell structured black TiO photocatalyst for environmental

期刊论文

Modeling of specific structure crystallization coupling with dissolution

Yuanhui JI, Hongliang QIAN, Chang LIU, Xiaohua LU, Xin FENG, Xiaoyan JI,

期刊论文